! $Id: fyhoro.f,v 1.1 2009/06/09 21:51:53 daven Exp $ !------------------------------------------------------------------------------ ! Harvard University Atmospheric Chemistry Modeling Group ! !------------------------------------------------------------------------------ !BOP ! ! !FUNCTION: FYHORO ! ! !DESCRIPTION: \subsection*{Overview} ! Function FYHORO returns returns the branching ratio between ! HOC2H4O oxidation and dissociation: ! (1) HOC2H4 --O2--> HO2 + GLYC ! (2) HOC2H4 ------> HO2 + 2CH2O !\subsection*{References} ! \begin{enumerate} ! \item Orlando et al., 1998: \emph{Laboratory and theoretical study of the ! oxyradicals in the OH- and Cl-initiated oxidation of ethene}, ! \underline{J. Phys. Chem. A}, \textbf{102}, 8116-8123. ! \item Orlando et al., 2003: \emph{The atmospheric chemistry of alkoxy ! radicals}, \underline{Chem. Rev.}, \textbf{103}, 4657-4689. ! \end{enumerate} ! !\\ !\\ ! !INTERFACE: ! REAL*8 FUNCTION FYHORO( ZDNUM, TT ) ! ! !USES: ! IMPLICIT NONE ! ! !INPUT PARAMETERS: ! ! Air density [molec/cm3 ] REAL*8, INTENT(IN) :: ZDNUM ! Temperature [K ] REAL*8, INTENT(IN) :: TT ! ! !REVISION HISTORY: ! (1 ) Branching ratio calculation (tmf, 2/6/05). !EOP !------------------------------------------------------------------------------ !BOC ! ! !LOCAL VARIABLES: ! REAL*8 :: K1, K2, O2DNUM !================================================================= ! FYHORO begins here! !================================================================= O2DNUM = ZDNUM * 0.21D0 K1 = 6.0D-14 * EXP(-550.D0/TT) * O2DNUM K2 = 9.5D+13 * EXP(-5988.D0/TT) FYHORO = K1 / (K1 + K2) ! Return to calling program END FUNCTION FYHORO !EOC