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GEOS-Chem-adjoint-v35-note/runs/v8-02-01/geos5/ratj.d
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# PHOTOLYSIS REACTIONS - MASTER RATEFILE - Paul Brown, Oliver Wild & David Rowley
# Centre for Atmospheric Science, Cambridge, U.K. Release date: 22 November 1993
# SCCS version information: @(#)photol.d 1.2 5/11/94
#
# Modified for Harvard chemistry: several reactions added, re-ordered per chem.dat
# Also putting in the Harvard names in col 1, the UCI x-sec names in last col !!!
# -Prashant Murti [4/13/98]
#
# The new peroxide recycling now activates the following photolysis species:
# GP,IAP,INPN,ISN1,ISNP,MAOP,MRP,PP,PRPN,RIP,VRP.
# Also be sure to set parameter JPMAX = 55 in "cmn_fj.h".
# - Randall Martin & Bob Yantosca [12/20/00]
# New updates from FASTJX.(jmao,ccarouge, 04/20/09)
#
# Harvard species Products - UCI notation UCI xsec
# =============== =============================== ========
1 H2O PHOTON OH HO2 0.00E+00 0.00 0.0
2 HO2 PHOTON OH O(3P) 0.00E+00 0.00 0.0
3 O2 PHOTON O(3P) O(3P) 0.00E+00 0.00 100.0 O2
4 O3_P PHOTON O2 O(3P) 0.00E+00 0.00 100.0 O3
5 O3 PHOTON O2 O(1D) 0.00E+00 0.00 100.0 O3_1d
6 NO2 PHOTON NO O(3P) 0.00E+00 0.00 100.0 NO2
7 H2O2 PHOTON OH OH 0.00E+00 0.00 100.0 H2O2
8 MP PHOTON HCHO OH HO2 0.00E+00 0.00 100.0 ROOH
9 CH2O PHOTON CO HO2 HO2 0.00E+00 0.00 100.0 HCHO=H+
10 CH2O PHOTON CO H2 0.00E+00 0.00 100.0 HCHO=H2
11 HNO3 PHOTON OH NO2 0.00E+00 0.00 100.0 HONO2
12 HNO2 PHOTON OH NO 0.00E+00 0.00 100.0 HONO
13 HNO4 PHOTON OH NO3 0.00E+00 0.00 33.3 HO2NO2
14 HNO4 PHOTON HO2 NO2 0.00E+00 0.00 66.7 HO2NO2
15 NO3 PHOTON NO O2 0.00E+00 0.00 100.0 NO3=O2+
16 NO3 PHOTON NO2 O(3P) 0.00E+00 0.00 100.0 NO3=O+
17 N2O5 PHOTON NO3 NO O(3P) 0.00E+00 0.00 0.0 N2O5
18 N2O5 PHOTON NO3 NO2 0.00E+00 0.00 100.0 N2O5
19 ALD2 PHOTON CH4 CO 0.00E+00 0.00 100.0 Acet=R+
20 ALD2 PHOTON MeOO HO2 CO 0.00E+00 0.00 100.0 Acet=RO
21 PAN PHOTON MeCO3 NO2 0.00E+00 0.00 100.0 PAN
22 RCHO PHOTON EtO2 HO2 CO 0.00E+00 0.00 100.0 RCHO
23 ACET PHOTON MeCO3 MeOO 0.00E+00 0.00 100.0 AcetA
24 ACET PHOTON MeOO MeOO CO 0.00E+00 0.00 100.0 AcetB
25 MEK PHOTON MeCO3 EtOO 0.00E+00 0.00 100.0 EtCOMe
26 MNO3 PHOTON HCHO H2O NO2 0.00E+00 0.00 100.0 MeNO3
27 GLYC PHOTON HCHO HO2 CO 0.00E+00 0.00 100.0 HOMeCHO
28 GLYX PHOTON H2 CO HCHO 0.00E+00 0.00 100.0 Glyxla
29 GLYX PHOTON CO HO2 0.00E+00 0.00 100.0 Glyxlb
30 MGLY PHOTON MeCO3 CO HO2 0.00E+00 0.00 100.0 MeCOCHO
31 MGLY PHOTON Acet CO 0.00E+00 0.00 0.0 MeCOCHO
32 MVK PHOTON PRPE CO 0.00E+00 0.00 60.0 MeCOVi
33 MVK PHOTON MeCO3 HCHO CO HO2 0.00E+00 0.00 20.0 MeCOVi
34 MVK PHOTON MeOO MAO3 0.00E+00 0.00 20.0 MeCOVi
35 MACR PHOTON MAO3 HO2 0.00E+00 0.00 50.0 MACR
36 MACR PHOTON CO HO2 MGLY HO2 MeCO3 HCHO 0.00E+00 0.00 50.0 MACR
37 HAC PHOTON MeCO3 HCHO HO2 0.00E+00 0.00 100.0 AcetA
38 ETP PHOTON OH HO2 Acet 0.00E+00 0.00 100.0 ROOH
39 RA3P PHOTON OH HO2 RCHO 0.00E+00 0.00 100.0 ROOH
40 RB3P PHOTON OH HO2 RCHO 0.00E+00 0.00 100.0 ROOH
41 R4P PHOTON OH HO2 RCHO 0.00E+00 0.00 100.0 ROOH
42 RP PHOTON OH HO2 Acet 0.00E+00 0.00 100.0 ROOH
43 R4N2 PHOTON NO2 MeCOMe MEK MO2 HO2 ALD2 ... 0.00E+00 0.00 100.0 MeNO3
44 MAP PHOTON OH MO2 0.00E+00 0.00 100.0 ROOH
45 INPN PHOTON OH HO2 RCHO NO2 0.00E+00 0.00 100.0 ROOH
46 PRPN PHOTON OH HO2 RCHO NO2 0.00E+00 0.00 100.0 ROOH
47 PP PHOTON OH HO2 RCHO 0.00E+00 0.00 100.0 ROOH
48 GP PHOTON OH HO2 RCHO 0.00E+00 0.00 100.0 ROOH
49 GLP PHOTON OH HO2 RCHO 0.00E+00 0.00 100.0 ROOH
50 RIP PHOTON OH HO2 CH2O MVK MACR RIO1 IALD 0.00E+00 0.00 100.0 ROOH
51 IAP PHOTON OH HO2 CO H2 HAC GLYC MGLY 0.00E+00 0.00 100.0 ROOH
52 ISNP PHOTON OH HO2 RCHO NO2 0.00E+00 0.00 100.0 ROOH
53 VRP PHOTON OH HO2 CH2O MCO3 GLYC MGLY 0.00E+00 0.00 100.0 ROOH
54 MRP PHOTON OH HO2 MGLY HAC CO CH2O 0.00E+00 0.00 100.0 ROOH
55 MAOP PHOTON OH HO2 RCHO 0.00E+00 0.00 100.0 ROOH
9999 0.00E-00 0.00 0.0
NOTES:
-----
[4/15/98]
Oliver Wild: All reaction data from JPL '97, IUPAC IV. IUPAC V is soon
expected. - ppm
All reaction data taken from IUPAC supplement IV unless otherwise indicated.
JPL - data from JPL (latest assessment as far as possible)
? - reaction products unknown
* - user strongly advised to consult source material
B - branching ratio assumed equal for all channels in the absence of more information
U - upper limit for rate coefficient
Changes since 08/3/93 release:
O now written as O(3P)
(Note that the second of the acetaldehyde channels above occurs at wavelengths
less than 289 nm, and therefore doesn't appear in the Fast-J region at all -
I've simply included it here for completeness) - [from Oliver, 3/7/98]