2223 lines
150 KiB
Plaintext
2223 lines
150 KiB
Plaintext
*** SMVGEAR II "globchem.dat" chemistry mechanism file (bdf, bmy, 6/19/06) ***
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***
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*** See http://www.env.leeds.ac.uk/~mat/GEOS-CHEM/GEOS-CHEM_Chemistry.htm
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*** for more information about individual species and reaction rates
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For GEOS-Chem v8-02-01 and higher (jmao, dbm, paul palmer, 4/20/09)
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==============================================================================
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(1) Updated available reactions from JPL06, IUPAC06
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(2) Updated acetaldehyde reactions updated by Dylan Millet
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(3) Updated some reactions inconsistent with Mat Evan's manual.
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For GEOS-CHEM v8-01-04 and higher (phs, 3/4/08)
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==============================================================================
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(1) Now includes emissions rxn for HNO3 and O3
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For GEOS-Chem v7-04-06 and higher (bastien, bmy, 6/19/06)
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==============================================================================
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(1) Turn off HO2 uptake by aerosols, in order to get better results in the
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tropics. Set the flag for the reaction HO2 -> 0.5 H2O2 from active ("A")
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to dead ("D"). SMVGEAR will then skip this reaction.
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For GEOS-Chem v7-04-05 and higher (dkh, bmy, 6/1/06)
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==============================================================================
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(1) Added LISOPOH as a species, to keep track of the amount of ISOP that
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is lost via rxn with OH. This is needed for the SOA chemistry.
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*** If you are running w/o the online SOA tracers, set LISOPOH to "D" ***
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*** If you are running w/ the online SOA tracers, set LISOPOH to "A" ***
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For GEOS-CHEM v5-07-06 and higher (rjp, bmy, 8/4/03)
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==============================================================================
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(1) Now also species declaration and rxn for DRYN2O5, since we are now
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doing N2O5 deposition. (bmy, 8/4/03)
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For GEOS-CHEM v5-07-05 and higher (mje, bmy, 8/1/03)
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==============================================================================
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(1) Now updated various rxn rates to JPL 2000. For more info see:
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www-as.harvard.edu/chemistry/trop/geos/documentation/geoschem_mech.pdf
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For GEOS-CHEM v5-05 (bdf, bmy, 4/10/03)
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==============================================================================
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(1) Now includes all of the same rxns from the SMVGEAR I "chem.dat" file
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from v5-03-01, including DMS and SO2 rxns.
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(2) Currently molecule mass is left out, this is needed for surface reactions
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(3) Mass balance is disabled, all inputs are zero.
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(4) Currently only 1 chemistry is used.
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(5) Currently not using "AB" that tells whether absorbs radiation.
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Our mechanism does this.
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#=============================================================================
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# Species List
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#=============================================================================
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BEGIN
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SUL NO3 NH4 CAR CHL BRO FLO HYD OXY
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A A A A A A A D D
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A A3O2 1.00 1.000E-20 1.000E-20 1.000E-20 1.000E-20
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0 0 0 0 0 0 0 0 0
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A ACET 1.00 1.000E-20 1.000E-20 1.000E-20 1.000E-20
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0 0 0 0 0 0 0 0 0
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I ACTA 1.00 1.000E-20 1.000E-20 1.000E-20 1.000E-20
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0 0 0 0 0 0 0 0 0
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A ALD2 1.00 1.000E-20 1.000E-20 1.000E-20 1.000E-20
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0 0 0 0 0 0 0 0 0
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A ALK4 1.00 1.000E-20 1.000E-20 1.000E-20 1.000E-20
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0 0 0 0 0 0 0 0 0
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A ATO2 1.00 1.000E-20 1.000E-20 1.000E-20 1.000E-20
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0 0 0 0 0 0 0 0 0
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A B3O2 1.00 1.000E-20 1.000E-20 1.000E-20 1.000E-20
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0 0 0 0 0 0 0 0 0
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A C2H6 1.00 1.000E-20 1.000E-20 1.000E-20 1.000E-20
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0 0 0 0 0 0 0 0 0
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A C3H8 1.00 1.000E-20 1.000E-20 1.000E-20 1.000E-20
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0 0 0 0 0 0 0 0 0
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A CH2O 1.00 4.000E-15 4.000E-15 4.000E-15 4.000E-15
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0 0 0 0 0 0 0 0 0
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I CH4 1.00 1.700E-06 1.700E-06 1.700E-06 1.700E-06
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0 0 0 0 0 0 0 0 0
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A CO 1.00 1.000E-07 1.000E-07 1.000E-07 1.000E-07
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0 0 0 0 0 0 0 0 0
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D CO2 1.00 3.550E-04 3.550E-04 3.550E-04 3.550E-04
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0 0 0 0 0 0 0 0 0
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A DRYCH2O 1.00 0.000E+00 0.000E+00 0.000E+00 0.000E+00
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0 0 0 0 0 0 0 0 0
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D DRYDEP 1.00 0.000E+00 0.000E+00 0.000E+00 0.000E+00
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0 0 0 0 0 0 0 0 0
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A DRYH2O2 1.00 0.000E+00 0.000E+00 0.000E+00 0.000E+00
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0 0 0 0 0 0 0 0 0
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A DRYHNO3 1.00 0.000E+00 0.000E+00 0.000E+00 0.000E+00
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0 0 0 0 0 0 0 0 0
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A DRYN2O5 1.00 0.000E+00 0.000E+00 0.000E+00 0.000E+00
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0 0 0 0 0 0 0 0 0
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A DRYNO2 1.00 0.000E+00 0.000E+00 0.000E+00 0.000E+00
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0 0 0 0 0 0 0 0 0
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A DRYO3 1.00 0.000E+00 0.000E+00 0.000E+00 0.000E+00
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0 0 0 0 0 0 0 0 0
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A DRYPAN 1.00 0.000E+00 0.000E+00 0.000E+00 0.000E+00
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0 0 0 0 0 0 0 0 0
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A DRYPMN 1.00 0.000E+00 0.000E+00 0.000E+00 0.000E+00
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0 0 0 0 0 0 0 0 0
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A DRYPPN 1.00 0.000E+00 0.000E+00 0.000E+00 0.000E+00
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0 0 0 0 0 0 0 0 0
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A DRYR4N2 1.00 0.000E+00 0.000E+00 0.000E+00 0.000E+00
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0 0 0 0 0 0 0 0 0
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I EMISSION 1.00 1.000E+00 1.000E+00 1.000E+00 1.000E+00
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0 0 0 0 0 0 0 0 0
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I EOH 1.00 1.000E-20 1.000E-20 1.000E-20 1.000E-20
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0 0 0 0 0 0 0 0 0
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A ETO2 1.00 1.000E-20 1.000E-20 1.000E-20 1.000E-20
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0 0 0 0 0 0 0 0 0
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A ETP 1.00 1.000E-20 1.000E-20 1.000E-20 1.000E-20
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0 0 0 0 0 0 0 0 0
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A GCO3 1.00 1.000E-20 1.000E-20 1.000E-20 1.000E-20
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0 0 0 0 0 0 0 0 0
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I GLCO3 1.00 1.000E-20 1.000E-20 1.000E-20 1.000E-20
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0 0 0 0 0 0 0 0 0
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I GLP 1.00 1.000E-20 1.000E-20 1.000E-20 1.000E-20
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0 0 0 0 0 0 0 0 0
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I GLPAN 1.00 1.000E-20 1.000E-20 1.000E-20 1.000E-20
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0 0 0 0 0 0 0 0 0
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A GLYC 1.00 1.000E-20 1.000E-20 1.000E-20 1.000E-20
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0 0 0 0 0 0 0 0 0
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I GLYX 1.00 1.000E-20 1.000E-20 1.000E-20 1.000E-20
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0 0 0 0 0 0 0 0 0
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A GP 1.00 1.000E-20 1.000E-20 1.000E-20 1.000E-20
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0 0 0 0 0 0 0 0 0
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A GPAN 1.00 1.000E-20 1.000E-20 1.000E-20 1.000E-20
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0 0 0 0 0 0 0 0 0
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I H 1.00 4.000E-20 4.000E-20 4.000E-20 4.000E-20
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0 0 0 0 0 0 0 0 0
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I H2 1.00 5.000E-07 5.000E-07 5.000E-07 5.000E-07
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0 0 0 0 0 0 0 0 0
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I H2O 1.00 1.839E-02 1.839E-02 1.839E-02 1.839E-02
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0 0 0 0 0 0 0 0 0
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A H2O2 1.00 4.000E-15 4.000E-15 4.000E-15 4.000E-15
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0 0 0 0 0 0 0 0 0
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A HAC 1.00 1.000E-20 1.000E-20 1.000E-20 1.000E-20
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0 0 0 0 0 0 0 0 0
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I HCOOH 1.00 1.000E-20 1.000E-20 1.000E-20 1.000E-20
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0 0 0 0 0 0 0 0 0
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A HNO2 1.00 4.000E-15 4.000E-15 4.000E-15 4.000E-15
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0 0 0 0 0 0 0 0 0
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A HNO3 1.00 4.000E-15 4.000E-15 4.000E-15 4.000E-15
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0 0 0 0 0 0 0 0 0
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A HNO4 1.00 4.000E-15 4.000E-15 4.000E-15 4.000E-15
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0 0 0 0 0 0 0 0 0
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A HO2 1.00 4.000E-15 4.000E-15 4.000E-15 4.000E-15
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0 0 0 0 0 0 0 0 0
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A IALD 1.00 1.000E-20 1.000E-20 1.000E-20 1.000E-20
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0 0 0 0 0 0 0 0 0
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A IAO2 1.00 1.000E-20 1.000E-20 1.000E-20 1.000E-20
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0 0 0 0 0 0 0 0 0
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A IAP 1.00 1.000E-20 1.000E-20 1.000E-20 1.000E-20
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0 0 0 0 0 0 0 0 0
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A INO2 1.00 1.000E-20 1.000E-20 1.000E-20 1.000E-20
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0 0 0 0 0 0 0 0 0
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A INPN 1.00 1.000E-20 1.000E-20 1.000E-20 1.000E-20
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0 0 0 0 0 0 0 0 0
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A ISN1 1.00 1.000E-20 1.000E-20 1.000E-20 1.000E-20
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0 0 0 0 0 0 0 0 0
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I ISNO3 1.00 1.000E-20 1.000E-20 1.000E-20 1.000E-20
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0 0 0 0 0 0 0 0 0
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A ISNP 1.00 1.000E-20 1.000E-20 1.000E-20 1.000E-20
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0 0 0 0 0 0 0 0 0
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A ISOP 1.00 1.000E-20 1.000E-20 1.000E-20 1.000E-20
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0 0 0 0 0 0 0 0 0
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A KO2 1.00 1.000E-20 1.000E-20 1.000E-20 1.000E-20
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0 0 0 0 0 0 0 0 0
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I M 1.00 0.000E+00 0.000E+00 0.000E+00 0.000E+00
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0 0 0 0 0 0 0 0 0
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A MACR 1.00 1.000E-20 1.000E-20 1.000E-20 1.000E-20
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0 0 0 0 0 0 0 0 0
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A MAN2 1.00 1.000E-20 1.000E-20 1.000E-20 1.000E-20
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0 0 0 0 0 0 0 0 0
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A MAO3 1.00 1.000E-20 1.000E-20 1.000E-20 1.000E-20
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0 0 0 0 0 0 0 0 0
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A MAOP 1.00 1.000E-20 1.000E-20 1.000E-20 1.000E-20
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0 0 0 0 0 0 0 0 0
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A MAP 1.00 1.000E-20 1.000E-20 1.000E-20 1.000E-20
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0 0 0 0 0 0 0 0 0
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A MCO3 1.00 1.000E-20 1.000E-20 1.000E-20 1.000E-20
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0 0 0 0 0 0 0 0 0
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A MEK 1.00 1.000E-20 1.000E-20 1.000E-20 1.000E-20
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0 0 0 0 0 0 0 0 0
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A MGLY 1.00 1.000E-20 1.000E-20 1.000E-20 1.000E-20
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0 0 0 0 0 0 0 0 0
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I MNO3 1.00 1.000E-20 1.000E-20 1.000E-20 1.000E-20
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0 0 0 0 0 0 0 0 0
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A MO2 1.00 4.000E-15 4.000E-15 4.000E-15 4.000E-15
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0 0 0 0 0 0 0 0 0
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I MOH 1.00 1.000E-20 1.000E-20 1.000E-20 1.000E-20
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0 0 0 0 0 0 0 0 0
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A MP 1.00 4.000E-15 4.000E-15 4.000E-15 4.000E-15
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0 0 0 0 0 0 0 0 0
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A MRO2 1.00 1.000E-20 1.000E-20 1.000E-20 1.000E-20
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0 0 0 0 0 0 0 0 0
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A MRP 1.00 1.000E-20 1.000E-20 1.000E-20 1.000E-20
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0 0 0 0 0 0 0 0 0
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A MVK 1.00 1.000E-20 1.000E-20 1.000E-20 1.000E-20
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0 0 0 0 0 0 0 0 0
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A MVN2 1.00 1.000E-20 1.000E-20 1.000E-20 1.000E-20
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0 0 0 0 0 0 0 0 0
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I N2 1.00 7.808E-01 7.808E-01 7.808E-01 7.808E-01
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0 0 0 0 0 0 0 0 0
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D N2O 1.00 3.000E-07 3.000E-07 3.000E-07 3.000E-07
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0 0 0 0 0 0 0 0 0
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A N2O5 1.00 4.000E-15 4.000E-15 4.000E-15 4.000E-15
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0 0 0 0 0 0 0 0 0
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I NH2 1.00 1.000E-20 1.000E-20 1.000E-20 1.000E-20
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0 0 0 0 0 0 0 0 0
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I NH3 1.00 1.000E-20 1.000E-20 1.000E-20 1.000E-20
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0 0 0 0 0 0 0 0 0
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A NO 1.00 4.000E-13 4.000E-13 4.000E-13 4.000E-13
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0 0 0 0 0 0 0 0 0
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A NO2 1.00 4.000E-13 4.000E-13 4.000E-13 4.000E-13
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0 0 0 0 0 0 0 0 0
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A NO3 1.00 4.000E-15 4.000E-15 4.000E-15 4.000E-15
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0 0 0 0 0 0 0 0 0
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I O 1.00 4.000E-20 4.000E-20 4.000E-20 4.000E-20
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0 0 0 0 0 0 0 0 0
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D O1D 1.00 4.000E-22 4.000E-22 4.000E-22 4.000E-22
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0 0 0 0 0 0 0 0 0
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I O2 1.00 2.095E-01 2.095E-01 2.095E-01 2.095E-01
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0 0 0 0 0 0 0 0 0
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I O2CH2OH 1.00 4.000E-20 4.000E-20 4.000E-20 4.000E-20
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0 0 0 0 0 0 0 0 0
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A O3 1.00 2.000E-08 2.000E-08 2.000E-08 2.000E-08
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0 0 0 0 0 0 0 0 0
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A OH 1.00 4.000E-15 4.000E-15 4.000E-15 4.000E-15
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0 0 0 0 0 0 0 0 0
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A PAN 1.00 1.000E-20 1.000E-20 1.000E-20 1.000E-20
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0 0 0 0 0 0 0 0 0
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A PMN 1.00 1.000E-20 1.000E-20 1.000E-20 1.000E-20
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0 0 0 0 0 0 0 0 0
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A PO2 1.00 1.000E-20 1.000E-20 1.000E-20 1.000E-20
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0 0 0 0 0 0 0 0 0
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A PP 1.00 1.000E-20 1.000E-20 1.000E-20 1.000E-20
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0 0 0 0 0 0 0 0 0
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A PPN 1.00 1.000E-20 1.000E-20 1.000E-20 1.000E-20
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0 0 0 0 0 0 0 0 0
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A PRN1 1.00 1.000E-20 1.000E-20 1.000E-20 1.000E-20
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0 0 0 0 0 0 0 0 0
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A PRPE 1.00 1.000E-20 1.000E-20 1.000E-20 1.000E-20
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0 0 0 0 0 0 0 0 0
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A PRPN 1.00 1.000E-20 1.000E-20 1.000E-20 1.000E-20
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0 0 0 0 0 0 0 0 0
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A R4N1 1.00 1.000E-20 1.000E-20 1.000E-20 1.000E-20
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0 0 0 0 0 0 0 0 0
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A R4N2 1.00 1.000E-20 1.000E-20 1.000E-20 1.000E-20
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0 0 0 0 0 0 0 0 0
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A R4O2 1.00 1.000E-20 1.000E-20 1.000E-20 1.000E-20
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0 0 0 0 0 0 0 0 0
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A R4P 1.00 1.000E-20 1.000E-20 1.000E-20 1.000E-20
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0 0 0 0 0 0 0 0 0
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A RA3P 1.00 1.000E-20 1.000E-20 1.000E-20 1.000E-20
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0 0 0 0 0 0 0 0 0
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A RB3P 1.00 1.000E-20 1.000E-20 1.000E-20 1.000E-20
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0 0 0 0 0 0 0 0 0
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A RCHO 1.00 1.000E-20 1.000E-20 1.000E-20 1.000E-20
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0 0 0 0 0 0 0 0 0
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A RCO3 1.00 1.000E-20 1.000E-20 1.000E-20 1.000E-20
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0 0 0 0 0 0 0 0 0
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I RCOOH 1.00 1.000E-20 1.000E-20 1.000E-20 1.000E-20
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0 0 0 0 0 0 0 0 0
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A RIO1 1.00 1.000E-20 1.000E-20 1.000E-20 1.000E-20
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0 0 0 0 0 0 0 0 0
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A RIO2 1.00 1.000E-20 1.000E-20 1.000E-20 1.000E-20
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0 0 0 0 0 0 0 0 0
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A RIP 1.00 1.000E-20 1.000E-20 1.000E-20 1.000E-20
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0 0 0 0 0 0 0 0 0
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I ROH 1.00 1.000E-20 1.000E-20 1.000E-20 1.000E-20
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0 0 0 0 0 0 0 0 0
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A RP 1.00 1.000E-20 1.000E-20 1.000E-20 1.000E-20
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0 0 0 0 0 0 0 0 0
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A VRO2 1.00 1.000E-20 1.000E-20 1.000E-20 1.000E-20
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0 0 0 0 0 0 0 0 0
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A VRP 1.00 1.000E-20 1.000E-20 1.000E-20 1.000E-20
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0 0 0 0 0 0 0 0 0
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A DMS 1.00 1.000E-20 1.000E-20 1.000E-20 1.000E-20
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0 0 0 0 0 0 0 0 0
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A SO2 1.00 1.000E-20 1.000E-20 1.000E-20 1.000E-20
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0 0 0 0 0 0 0 0 0
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A SO4 1.00 1.000E-20 1.000E-20 1.000E-20 1.000E-20
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0 0 0 0 0 0 0 0 0
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A MSA 1.00 1.000E-20 1.000E-20 1.000E-20 1.000E-20
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0 0 0 0 0 0 0 0 0
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D LISOPOH 1.00 1.000E-20 1.000E-20 1.000E-20 1.000E-20
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0 0 0 0 0 0 0 0 0
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END
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#=============================================================================
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# Kinetic reactions
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#=============================================================================
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BEGIN
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A 21 3.00E-12 0.0E+00 -1500 0 0.00 0. 0.
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O3 + NO
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=1.000NO2 +1.000O2 + +
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+ + + +
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+ + + +
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+ + + +
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A 26 1.70E-12 0.0E+00 -940 0 0.00 0. 0.
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O3 + OH
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=1.000HO2 +1.000O2 + +
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+ + + +
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+ + + +
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+ + + +
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A 27 1.00E-14 0.0E+00 -490 0 0.00 0. 0.
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O3 + HO2
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=1.000OH +1.000O2 +1.000O2 +
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+ + + +
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+ + + +
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+ + + +
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A 28 1.20E-13 0.0E+00 -2450 0 0.00 0. 0.
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O3 + NO2
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=1.000O2 +1.000NO3 + +
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+ + + +
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+ + + +
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+ + + +
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A 29 2.90E-16 0.0E+00 -1000 0 0.00 0. 0.
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O3 + MO2
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=1.000CH2O +1.000HO2 +2.000O2 +
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+ + + +
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+ + + +
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|
+ + + +
|
|
A 39 1.80E-12 0.0E+00 0 0 0.00 0. 0.
|
|
OH + OH
|
|
=1.000H2O +1.000O3 + +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 32 6.90E-31 1.0E+00 0 1 P 0.60 0. 0.
|
|
2.60E-11 0.0E+00 0 0 0.00 0. 0.
|
|
OH + OH M
|
|
=1.000H2O2 + + +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 40 4.80E-11 0.0E+00 250 0 0.00 0. 0.
|
|
OH + HO2
|
|
=1.000H2O +1.000O2 + +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 41 1.80E-12 0.0E+00 0 0 0.00 0. 0.
|
|
OH + H2O2
|
|
=1.000H2O +1.000HO2 + +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 42 3.50E-12 0.0E+00 250 0 0.00 0. 0.
|
|
HO2 + NO
|
|
=1.000OH +1.000NO2 + +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 44 3.50E-13 0.0E+00 430 1 Z 0.00 0. 0.
|
|
1.70E-33 0.0E+00 1000 0 0.00 0. 0.
|
|
HO2 + HO2
|
|
=1.000H2O2 + + +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 47 2.80E-12 0.0E+00 -1800 0 0.00 0. 0.
|
|
OH + H2
|
|
=1.000H2O +1.000HO2 + +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 48 1.50E-13 0.0E+00 0 0 Y 0.00 0. 0.
|
|
CO + OH
|
|
=1.000HO2 +1.000CO2 + +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 49 2.45E-12 0.0E+00 -1775 0 0.00 0. 0.
|
|
OH + CH4
|
|
=1.000MO2 +1.000H2O + +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 51 2.80E-12 0.0E+00 300 0 0.00 0. 0.
|
|
MO2 + NO
|
|
=1.000CH2O +1.000HO2 +1.000NO2 +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 52 4.10E-13 0.0E+00 750 0 0.00 0. 0.
|
|
MO2 + HO2
|
|
=1.000MP +1.000O2 + +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
D 52 4.10E-13 0.0E+00 750 1 V 0.00 0. 0.
|
|
4.98E+02 0.0E+00 -1160 0 0.00 0. 0.
|
|
MO2 + HO2
|
|
=1.000CH2O +1.000O2 + +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 53 9.50E-14 0.0E+00 390 1 V 0.00 0. 0.
|
|
2.62E+01 0.0E+00 -1130 0 0.00 0. 0.
|
|
MO2 + MO2
|
|
=1.000MOH +1.000CH2O +1.000O2 +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 53 9.50E-14 0.0E+00 390 1 V 0.00 0. 0.
|
|
4.00E-02 0.0E+00 1130 0 0.00 0. 0.
|
|
MO2 + MO2
|
|
=2.000CH2O +2.000HO2 + +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 55 2.66E-12 0.0E+00 200 0 0.00 0. 0.
|
|
MP + OH
|
|
=1.000MO2 +1.000H2O + +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 57 1.14E-12 0.0E+00 200 0 0.00 0. 0.
|
|
MP + OH
|
|
=1.000CH2O +1.000OH +1.000H2O +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 58 5.50E-12 0.0E+00 125 0 0.00 0. 0.
|
|
CH2O + OH
|
|
=1.000CO +1.000HO2 +1.000H2O +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 62 1.80E-30 3.0E+00 0 1 P 0.60 0. 0.
|
|
2.80E-11 0.0E+00 0 0 P 0.00 0. 0.
|
|
NO2 + OH M
|
|
=1.000HNO3 +1.000M + +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 64 2.41E-14 0.0E+00 460 2 X 0.00 0. 0.
|
|
2.69E-17 0.0E+00 2199 0 0.00 0. 0.
|
|
6.51E-34 0.0E+00 1335 0 0.00 0. 0.
|
|
HNO3 + OH
|
|
=1.000H2O +1.000NO3 + +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 67 7.00E-31 2.6E+00 0 1 P 0.60 0. 0.
|
|
3.60E-11 1.0E-01 0 0 0.00 0. 0.
|
|
NO + OH M
|
|
=1.000HNO2 +1.000M + +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 70 1.80E-11 0.0E+00 -390 0 0.00 0. 0.
|
|
HNO2 + OH
|
|
=1.000H2O +1.000NO2 + +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 72 2.00E-31 3.4E+00 0 1 P 0.60 0. 0.
|
|
2.90E-12 1.1E+00 0 0 0.00 0. 0.
|
|
HO2 + NO2 M
|
|
=1.000HNO4 +1.000M + +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 73 9.52E-05 3.2E+00 -10900 1 P 0.60 0. 0.
|
|
1.38E+15 1.4E+00 -10900 0 0.00 0. 0.
|
|
HNO4 + M
|
|
=1.000HO2 +1.000NO2 + +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 76 1.30E-12 0.0E+00 380 0 0.00 0. 0.
|
|
HNO4 + OH
|
|
=1.000H2O +1.000NO2 +1.000O2 +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 0 3.50E-12 0.0E+00 0 0 0.00 0. 0.
|
|
HO2 + NO3
|
|
=1.000OH +1.000NO2 +1.000O2 +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 79 1.50E-11 0.0E+00 170 0 0.00 0. 0.
|
|
NO + NO3
|
|
=2.000NO2 + + +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 0 2.20E-11 0.0E+00 0 0 0.00 0. 0.
|
|
OH + NO3
|
|
=1.000HO2 +1.000NO2 + +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 82 2.00E-30 4.4E+00 0 1 P 0.60 0. 0.
|
|
1.40E-12 7.0E-01 0 0 0.00 0. 0.
|
|
NO2 + NO3 M
|
|
=1.000N2O5 +1.000M + +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 83 7.40E-04 4.4E+00 -11000 1 P 0.60 0. 0.
|
|
5.18E+14 7.0E-01 -11000 0 0.00 0. 0.
|
|
N2O5 + M
|
|
=1.000NO2 +1.000NO3 + +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 159 4.00E-13 0.0E+00 0 0 0.00 0. 0.
|
|
HCOOH + OH
|
|
=1.000H2O +1.000CO2 +1.000HO2 +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 188 2.90E-12 0.0E+00 -345 0 0.00 0. 0.
|
|
MOH + OH
|
|
=1.000HO2 +1.000CH2O + +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 407 4.50E-14 0.0E+00 -1260 0 0.00 0. 0.
|
|
NO2 + NO3
|
|
=1.000NO +1.000NO2 +1.000O2 +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 437 5.80E-16 0.0E+00 0 0 0.00 0. 0.
|
|
NO3 + CH2O
|
|
=1.000HNO3 +1.000HO2 +1.000CO +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 438 4.40E-12 0.0E+00 365 0 0.00 0. 0.
|
|
ALD2 + OH
|
|
=0.950MCO3 +0.050CH2O +0.050CO +
|
|
+0.050HO2 + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 439 1.40E-12 0.0E+00 -1900 0 0.00 0. 0.
|
|
ALD2 + NO3
|
|
=1.000HNO3 +1.000MCO3 + +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 442 9.70E-29 5.6E+00 0 1 P 0.60 0. 0.
|
|
9.30E-12 1.5E+00 0 0 0.00 0. 0.
|
|
MCO3 + NO2 M
|
|
=1.000PAN + + +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 442 9.30E-29 0.0E+00 14000 0 E 0.00 0. 0.
|
|
PAN +
|
|
=1.000MCO3 +1.000NO2 + +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 444 8.10E-12 0.0E+00 270 0 0.00 0. 0.
|
|
MCO3 + NO
|
|
=1.000MO2 +1.000NO2 +1.000CO2 +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 447 8.70E-12 0.0E+00 -1070 0 0.00 0. 0.
|
|
C2H6 + OH
|
|
=1.000ETO2 +1.000H2O + +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 448 2.60E-12 0.0E+00 365 0 0.00 0. 0.
|
|
ETO2 + NO
|
|
=1.000ALD2 +1.000NO2 +1.000HO2 +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 53 7.60E-12 0.0E+00 -585 1 V 0.00 0. 0.
|
|
5.87E+00 6.4E-01 -816 0 0.00 0. 0.
|
|
C3H8 + OH
|
|
=1.000B3O2 + + +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 53 7.60E-12 0.0E+00 -585 1 V 0.00 0. 0.
|
|
0.17E+00 -6.4E-01 816 0 0.00 0. 0.
|
|
C3H8 + OH
|
|
=1.000A3O2 + + +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 450 2.90E-12 0.0E+00 350 0 0.00 0. 0.
|
|
A3O2 + NO
|
|
=1.000NO2 +1.000HO2 +1.000RCHO +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 450 2.70E-12 0.0E+00 350 0 0.00 0. 0.
|
|
PO2 + NO
|
|
=1.000NO2 +1.000HO2 +1.000CH2O +1.000ALD2
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 452 9.10E-12 0.0E+00 -405 0 0.00 0. 0.
|
|
ALK4 + OH
|
|
=1.000R4O2 + + +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 453 2.70E-12 0.0E+00 350 1 B 0.00 0. 0.
|
|
4.50E+00 0.0E+00 0 0 0.00 0. 0.
|
|
R4O2 + NO
|
|
=1.000NO2 +0.320ACET +0.190MEK +0.180MO2
|
|
+0.270HO2 +0.320ALD2 +0.130RCHO +0.050A3O2
|
|
+0.180B3O2 +0.320ETO2 + +
|
|
+ + + +
|
|
A 453 2.70E-12 0.0E+00 350 1 A 0.00 0. 0.
|
|
4.50E+00 0.0E+00 0 0 0.00 0. 0.
|
|
R4O2 + NO
|
|
=1.000R4N2 + + +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 453 2.70E-12 0.0E+00 350 0 0.00 0. 0.
|
|
R4N1 + NO
|
|
=2.000NO2 +0.390CH2O +0.750ALD2 +0.570RCHO
|
|
+0.300R4O2 + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 453 2.80E-12 0.0E+00 300 0 0.00 0. 0.
|
|
ATO2 + NO
|
|
=0.960NO2 +0.960CH2O +0.960MCO3 +0.040R4N2
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 453 2.70E-12 0.0E+00 350 0 0.00 0. 0.
|
|
KO2 + NO
|
|
=0.930NO2 +0.930ALD2 +0.930MCO3 +0.070R4N2
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 453 2.70E-12 0.0E+00 350 0 0 0.00 0. 0.
|
|
RIO2 + NO
|
|
=0.900NO2 +0.900HO2 +0.340IALD +0.340MVK
|
|
+0.220MACR +0.560CH2O + +
|
|
+ + + +
|
|
+ + + +
|
|
A 453 2.70E-12 0.0E+00 350 1 A 0.00 0. 0.
|
|
5.00E+00 0.0E+00 0 0 0.00 0. 0.
|
|
RIO2 + NO
|
|
=1.000HNO3 + + +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 453 2.70E-12 0.0E+00 350 1 B 0.00 0. 0.
|
|
5.00E+00 0.0E+00 0 0 0.00 0. 0.
|
|
RIO1 + NO
|
|
=1.000NO2 +1.000IALD +1.000HO2 +0.750CH2O
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 453 2.70E-12 0.0E+00 350 1 A 0.00 0. 0.
|
|
5.00E+00 0.0E+00 0 0 0.00 0. 0.
|
|
RIO1 + NO
|
|
=1.000HNO3 + + +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 453 2.70E-12 0.0E+00 350 0 0.00 0. 0.
|
|
IAO2 + NO
|
|
=0.920HO2 +0.610CO +0.170H2 +0.330HAC
|
|
+0.240GLYC +0.530MGLY +0.920NO2 +0.350CH2O
|
|
+0.080HNO3 + + +
|
|
+ + + +
|
|
A 453 2.70E-12 0.0E+00 350 0 0.00 0. 0.
|
|
ISN1 + NO
|
|
=1.900NO2 +0.950GLYC +0.950HAC +0.050HNO3
|
|
+0.050NO2 +0.050HO2 + +
|
|
+ + + +
|
|
+ + + +
|
|
A 453 2.70E-12 0.0E+00 350 1 B 0.00 0. 0.
|
|
4.00E+00 0.0E+00 0 0 0.00 0. 0.
|
|
VRO2 + NO
|
|
=1.000NO2 +0.280HO2 +0.280CH2O +0.720MCO3
|
|
+0.720GLYC +0.280MGLY + +
|
|
+ + + +
|
|
+ + + +
|
|
A 453 2.70E-12 0.0E+00 350 1 A 0.00 0. 0.
|
|
4.00E+00 0.0E+00 0 0 0.00 0. 0.
|
|
VRO2 + NO
|
|
=1.000HNO3 + + +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 453 2.70E-12 0.0E+00 350 1 B 0.00 0. 0.
|
|
4.00E+00 0.0E+00 0 0 0.00 0. 0.
|
|
MRO2 + NO
|
|
=1.000NO2 +1.000HO2 +1.000HAC +1.000CH2O
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 453 2.70E-12 0.0E+00 350 1 A 0.00 0. 0.
|
|
4.00E+00 0.0E+00 0 0 0.00 0. 0.
|
|
MRO2 + NO
|
|
=1.000HNO3 + + +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 453 2.70E-12 0.0E+00 350 0 0.00 0. 0.
|
|
MVN2 + NO
|
|
=1.900NO2 +0.300HO2 +0.300CH2O +0.600MCO3
|
|
+0.600GLYC +0.300MGLY +0.100HNO3 +
|
|
+ + + +
|
|
+ + + +
|
|
A 453 2.70E-12 0.0E+00 350 0 0.00 0. 0.
|
|
MAN2 + NO
|
|
=2.000NO2 +1.000CH2O +1.000MGLY +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 453 2.70E-12 0.0E+00 350 0 0.00 0. 0.
|
|
B3O2 + NO
|
|
=1.000NO2 +1.000HO2 +1.000ACET +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 453 2.70E-12 0.0E+00 350 0 0.00 0. 0.
|
|
INO2 + NO
|
|
=1.100NO2 +0.800HO2 +0.850HNO3 +0.050NO2
|
|
+0.100MACR +0.150CH2O +0.050MVK +
|
|
+ + + +
|
|
+ + + +
|
|
A 453 2.70E-12 0.0E+00 350 0 0.00 0. 0.
|
|
PRN1 + NO
|
|
=2.000NO2 +1.000CH2O +1.000ALD2 +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 455 2.80E-12 0.0E+00 -3280 0 0.00 0. 0.
|
|
ALK4 + NO3
|
|
=1.000HNO3 +1.000R4O2 + +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 456 1.60E-12 0.0E+00 0 0 0.00 0. 0.
|
|
R4N2 + OH
|
|
=1.000R4N1 +1.000H2O + +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 459 4.20E-14 0.0E+00 855 0 0.00 0. 0.
|
|
ACTA + OH
|
|
=1.000MO2 +1.000CO2 +1.000H2O +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 463 6.00E-12 0.0E+00 410 0 0.00 0. 0.
|
|
OH + RCHO
|
|
=1.000RCO3 +1.000H2O + +
|
|
+ + + +
|
|
+ + + +
|
|
+
|
|
A 442 9.00E-28 8.9E+00 0 1 P 0.60 0. 0.
|
|
7.70E-12 0.2E+00 0 0 0.00 0. 0.
|
|
RCO3 + NO2 M
|
|
=1.000PPN + + +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 465 9.00E-29 0.0E+00 14000 0 E 0.00 0. 0.
|
|
PPN +
|
|
=1.000RCO3 +1.000NO2 + +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 442 9.00E-28 8.9E+00 0 1 P 0.60 0. 0.
|
|
7.70E-12 0.2E+00 0 0 0.00 0. 0.
|
|
GCO3 + NO2 M
|
|
=1.000GPAN + + +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 465 9.00E-29 0.0E+00 14000 0 E 0.00 0. 0.
|
|
GPAN +
|
|
=1.000GCO3 +1.000NO2 + +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 442 9.00E-28 8.9E+00 0 1 P 0.60 0. 0.
|
|
7.70E-12 0.2E+00 0 0 0.00 0. 0.
|
|
MAO3 + NO2 M
|
|
=1.000PMN + + +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 465 9.00E-29 0.0E+00 14000 0 E 0.00 0. 0.
|
|
PMN +
|
|
=1.000MAO3 +1.000NO2 + +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 442 9.00E-28 8.9E+00 0 1 P 0.60 0. 0.
|
|
7.70E-12 0.2E+00 0 0 0.00 0. 0.
|
|
GLCO3 + NO2 M
|
|
=1.000GLPAN + + +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 465 9.00E-29 0.0E+00 14000 0 E 0.00 0. 0.
|
|
GLPAN +
|
|
=1.000GLCO3 +1.000NO2 + +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 466 6.70E-12 0.0E+00 340 0 0.00 0. 0.
|
|
RCO3 + NO
|
|
=1.000NO2 +1.000ETO2 + +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 466 6.70E-12 0.0E+00 340 0 0.00 0. 0.
|
|
GCO3 + NO
|
|
=1.000NO2 +1.000HO2 +1.000CH2O +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 466 6.70E-12 0.0E+00 340 0 0.00 0. 0.
|
|
MAO3 + NO
|
|
=1.000NO2 +1.000CH2O +1.000MCO3 +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 466 8.10E-12 0.0E+00 270 0 0.00 0. 0.
|
|
GLCO3 + NO
|
|
=1.000NO2 +1.000HO2 +1.000CO +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 468 6.50E-15 0.0E+00 0 0 0.00 0. 0.
|
|
RCHO + NO3
|
|
=1.000HNO3 +1.000RCO3 + +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 470 1.33E-13 0.0E+00 0 0 0.00 0. 0.
|
|
ACET + OH
|
|
=1.000ATO2 +1.000H2O + +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 470 3.82E-11 0.0E+00 -2000 0 0.00 0. 0.
|
|
ACET + OH
|
|
=1.000ATO2 +1.000H2O + +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 471 5.92E-13 0.0E+00 0 0 0.00 0. 0.
|
|
A3O2 + MO2
|
|
=1.000HO2 +0.750CH2O +0.750RCHO +0.250MOH
|
|
+0.250ROH + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 471 5.92E-13 0.0E+00 0 0 0.00 0. 0.
|
|
PO2 + MO2
|
|
=1.000HO2 +0.500ALD2 +1.250CH2O +0.160HAC
|
|
+0.090RCHO +0.250MOH +0.250ROH +
|
|
+ + + +
|
|
+ + + +
|
|
A 472 7.40E-13 0.0E+00 700 0 0.00 0. 0.
|
|
R4O2 + HO2
|
|
=1.000R4P + + +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 472 7.40E-13 0.0E+00 700 0 0.00 0. 0.
|
|
R4N1 + HO2
|
|
=1.000R4N2 + + +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 472 8.60E-13 0.0E+00 700 0 0.00 0. 0.
|
|
ATO2 + HO2
|
|
=1.000MCO3 +1.000MO2 + +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 472 7.40E-13 0.0E+00 700 0 0.00 0. 0.
|
|
KO2 + HO2
|
|
=1.000MO2 +1.000MGLY + +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 472 7.40E-13 0.0E+00 700 0 0.00 0. 0.
|
|
RIO2 + HO2
|
|
=1.000RIP + + +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 472 7.40E-13 0.0E+00 700 0 0.00 0. 0.
|
|
RIO1 + HO2
|
|
=1.000RIP + + +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 472 7.40E-13 0.0E+00 700 0 0.00 0. 0.
|
|
IAO2 + HO2
|
|
=1.000IAP + + +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 472 7.40E-13 0.0E+00 700 0 0.00 0. 0.
|
|
ISN1 + HO2
|
|
=1.000ISNP + + +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 472 7.40E-13 0.0E+00 700 0 0.00 0. 0.
|
|
VRO2 + HO2
|
|
=1.000VRP + + +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 472 7.40E-13 0.0E+00 700 0 0.00 0. 0.
|
|
MRO2 + HO2
|
|
=1.000MRP + + +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 472 7.40E-13 0.0E+00 700 0 0.00 0. 0.
|
|
MVN2 + HO2
|
|
=1.000ISNP + + +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 472 7.40E-13 0.0E+00 700 0 0.00 0. 0.
|
|
MAN2 + HO2
|
|
=1.000ISNP + + +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 472 7.40E-13 0.0E+00 700 0 0.00 0. 0.
|
|
B3O2 + HO2
|
|
=1.000RB3P + + +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 472 7.40E-13 0.0E+00 700 0 0.00 0. 0.
|
|
INO2 + HO2
|
|
=1.000INPN + + +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 472 7.40E-13 0.0E+00 700 0 0.00 0. 0.
|
|
PRN1 + HO2
|
|
=1.000PRPN + + +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 473 1.30E-12 0.0E+00 -25 0 0.00 0. 0.
|
|
MEK + OH
|
|
=1.000KO2 +1.000H2O + +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 474 3.00E-13 0.0E+00 0 0 0.00 0. 0.
|
|
MO2 + ETO2
|
|
=0.750CH2O +0.750ALD2 +1.000HO2 +0.250MOH
|
|
+0.250EOH + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 476 8.00E-16 0.0E+00 0 0 0.00 0. 0.
|
|
MEK + NO3
|
|
=1.000HNO3 +1.000KO2 + +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 478 8.37E-14 0.0E+00 0 0 0.00 0. 0.
|
|
R4O2 + MO2
|
|
=0.160ACET +0.100MEK +0.090MO2 +0.140HO2
|
|
+0.160ALD2 +0.070RCHO +0.030A3O2 +0.090B3O2
|
|
+0.160ETO2 +0.250MEK +0.750CH2O +0.250MOH
|
|
+0.250ROH +0.500HO2 + +
|
|
A 478 8.37E-14 0.0E+00 0 0 0.00 0. 0.
|
|
R4N1 + MO2
|
|
=1.000NO2 +0.200CH2O +0.380ALD2 +0.290RCHO
|
|
+0.150R4O2 +0.250RCHO +0.750CH2O +0.250MOH
|
|
+0.250ROH +0.500HO2 + +
|
|
+ + + +
|
|
A 478 7.50E-13 0.0E+00 500 0 0.00 0. 0.
|
|
ATO2 + MO2
|
|
=0.300HO2 +0.300CH2O +0.300MCO3 +0.200HAC
|
|
+0.200CH2O +0.500MGLY +0.500MOH +
|
|
+ + + +
|
|
+ + + +
|
|
A 478 8.37E-14 0.0E+00 0 0 0.00 0. 0.
|
|
KO2 + MO2
|
|
=0.500ALD2 +0.500MCO3 +0.250MEK +0.750CH2O
|
|
+0.250MOH +0.250ROH +0.500HO2 +
|
|
+ + + +
|
|
+ + + +
|
|
A 478 8.37E-14 0.0E+00 0 0 0.00 0. 0.
|
|
RIO2 + MO2
|
|
=0.420HO2 +0.350CH2O +0.200MVK +0.140MACR
|
|
+0.070RIO1 +0.060IALD +0.250MEK +0.750CH2O
|
|
+0.250MOH +0.250ROH +0.500HO2 +
|
|
+ + + +
|
|
A 478 8.37E-14 0.0E+00 0 0 0.00 0. 0.
|
|
RIO1 + MO2
|
|
=0.500IALD +0.500HO2 +0.380CH2O +0.250MEK
|
|
+0.750CH2O +0.250MOH +0.250ROH +0.500HO2
|
|
+ + + +
|
|
+ + + +
|
|
A 478 8.37E-14 0.0E+00 0 0 0.00 0. 0.
|
|
IAO2 + MO2
|
|
=0.500HO2 +0.330CO +0.090H2 +0.180HAC
|
|
+0.130GLYC +0.290MGLY +0.250MEK +0.950CH2O
|
|
+0.250MOH +0.250ROH +0.500HO2 +
|
|
+ + + +
|
|
A 478 8.37E-14 0.0E+00 0 0 0.00 0. 0.
|
|
ISN1 + MO2
|
|
=1.000NO2 +0.500GLYC +0.500HAC +0.250RCHO
|
|
+0.750CH2O +0.250MOH +0.250ROH +0.500HO2
|
|
+ + + +
|
|
+ + + +
|
|
A 478 8.37E-14 0.0E+00 0 0 0.00 0. 0.
|
|
VRO2 + MO2
|
|
=0.140HO2 +0.140CH2O +0.360MCO3 +0.360GLYC
|
|
+0.140MGLY +0.250MEK +0.750CH2O +0.250MOH
|
|
+0.250ROH +0.500HO2 + +
|
|
+ + + +
|
|
A 478 8.37E-14 0.0E+00 0 0 0.00 0. 0.
|
|
MRO2 + MO2
|
|
=1.000HAC +0.850CH2O +1.150HO2 +0.150CO
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 478 8.37E-14 0.0E+00 0 0 0.00 0. 0.
|
|
MVN2 + MO2
|
|
=1.000NO2 +0.500CH2O +0.250MCO3 +0.250MGLY
|
|
+0.250HO2 +0.250RCHO +0.750CH2O +0.250MOH
|
|
+0.250ROH +0.500HO2 + +
|
|
+ + + +
|
|
A 478 8.37E-14 0.0E+00 0 0 0.00 0. 0.
|
|
MAN2 + MO2
|
|
=1.000NO2 +0.500CH2O +0.500MGLY +0.250RCHO
|
|
+0.750CH2O +0.250MOH +0.250ROH +0.500HO2
|
|
+ + + +
|
|
+ + + +
|
|
A 478 8.37E-14 0.0E+00 0 0 0.00 0. 0.
|
|
B3O2 + MO2
|
|
=0.500HO2 +0.500ACET +0.250ACET +0.750CH2O
|
|
+0.250MOH +0.250ROH +0.500HO2 +
|
|
+ + + +
|
|
+ + + +
|
|
A 478 8.37E-14 0.0E+00 0 0 0.00 0. 0.
|
|
INO2 + MO2
|
|
=0.550NO2 +0.400HO2 +0.425HNO3 +0.025NO2
|
|
+0.050MACR +0.080CH2O +0.030MVK +0.250RCHO
|
|
+0.750CH2O +0.250MOH +0.250ROH +0.050HO2
|
|
+ + + +
|
|
A 478 8.37E-14 0.0E+00 0 0 0.00 0. 0.
|
|
PRN1 + MO2
|
|
=1.000NO2 +0.500CH2O +0.500ALD2 +0.250RCHO
|
|
+0.750CH2O +0.250MOH +0.250ROH +0.500HO2
|
|
+ + + +
|
|
+ + + +
|
|
A 479 6.90E-12 0.0E+00 -230 0 0.00 0. 0.
|
|
EOH + OH
|
|
=1.000HO2 +1.000ALD2 + +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 480 4.60E-12 0.0E+00 70 0 0.00 0. 0.
|
|
ROH + OH
|
|
=1.000HO2 +1.000RCHO + +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 481 4.10E-14 0.0E+00 0 0 0.00 0. 0.
|
|
ETO2 + ETO2
|
|
=2.000ALD2 +2.000HO2 + +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 481 2.70E-14 0.0E+00 0 0 0.00 0. 0.
|
|
ETO2 + ETO2
|
|
=1.000EOH +1.000ALD2 + +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 485 7.40E-13 0.0E+00 700 0 0.00 0. 0.
|
|
HO2 + ETO2
|
|
=1.000ETP + + +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 486 7.40E-13 0.0E+00 700 0 0.00 0. 0.
|
|
A3O2 + HO2
|
|
=1.000RA3P + + +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 486 7.40E-13 0.0E+00 700 0 0.00 0. 0.
|
|
PO2 + HO2
|
|
=1.000PP + + +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 490 5.20E-13 0.0E+00 980 0 0.00 0. 0.
|
|
HO2 + MCO3
|
|
=0.150ACTA +0.150O3 +0.440OH +0.440MO2
|
|
+0.410MAP + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 491 4.30E-13 0.0E+00 1040 0 0.00 0. 0.
|
|
RCO3 + HO2
|
|
=0.300RCOOH +0.300O3 +0.700RP +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 491 4.30E-13 0.0E+00 1040 0 0.00 0. 0.
|
|
GCO3 + HO2
|
|
=0.290CH2O +0.290O3 +0.710GP +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 491 4.30E-13 0.0E+00 1040 0 0.00 0. 0.
|
|
MAO3 + HO2
|
|
=0.300RCOOH +0.300O3 +0.700MAOP +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 491 4.30E-13 0.0E+00 1040 0 0.00 0. 0.
|
|
GLCO3 + HO2
|
|
=0.300RCOOH +0.300O3 +0.700GLP +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 494 8.00E-27 3.5E+00 0 1 P 0.50 0. 0.
|
|
3.00E-11 1.0E+00 0 0 0.00 0. 0.
|
|
PRPE + OH M
|
|
=1.000PO2 + + +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 497 5.50E-15 0.0E+00 -1880 0 0.00 0. 0.
|
|
PRPE + O3
|
|
=0.535CH2O +0.500ALD2 +0.420CO +0.300HO2
|
|
+0.135OH +0.065H2 +0.305MO2 +
|
|
+ + + +
|
|
+ + + +
|
|
A 504 3.20E-11 0.0E+00 0 0 0.00 0. 0.
|
|
PMN + OH
|
|
=1.000NO2 +0.590HAC +2.000HO2 +2.230CH2O
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 505 8.20E-18 0.0E+00 0 0 0.00 0. 0.
|
|
PMN + O3
|
|
=1.000NO2 +0.600CH2O +1.000HO2 +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 506 1.00E-11 0.0E+00 0 0 0.00 0. 0.
|
|
GLYC + OH
|
|
=0.800GCO3 +0.400CO +0.200H2 +0.200HO2
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 517 4.59E-13 0.0E+00 -1156 0 0.00 0. 0.
|
|
PRPE + NO3
|
|
=1.000PRN1 + + +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 534 1.10E-11 0.0E+00 0 0 C 0.00 0. 0.
|
|
GLYX + OH
|
|
=1.000HO2 +2.000CO + +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 536 1.50E-11 0.0E+00 0 0 0.00 0. 0.
|
|
MGLY + OH
|
|
=1.000MCO3 +1.000CO + +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 581 1.40E-12 0.0E+00 -1860 0 C 0.00 0. 0.
|
|
GLYX + NO3
|
|
=1.000HNO3 +1.000HO2 +2.000CO +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 582 1.40E-12 0.0E+00 -1860 0 0.00 0. 0.
|
|
MGLY + NO3
|
|
=1.000HNO3 +1.000CO +1.000MCO3 +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 587 2.70E-11 0.0E+00 390 0 0.00 0. 0.
|
|
ISOP + OH
|
|
=1.000RIO2 +1.000LISOPOH + +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 590 2.60E-12 0.0E+00 610 0 0.00 0. 0.
|
|
MVK + OH
|
|
=1.000VRO2 + + +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 593 8.00E-12 0.0E+00 380 0 0.00 0. 0.
|
|
MACR + OH
|
|
=0.570MAO3 +0.430MRO2 + +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 596 3.00E-12 0.0E+00 0 0 0.00 0. 0.
|
|
HAC + OH
|
|
=1.000MGLY +1.000HO2 + +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 597 1.68E-12 0.0E+00 500 0 0.00 0. 0.
|
|
MCO3 + A3O2
|
|
=1.000MO2 +1.000RCHO +1.000HO2 +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 597 1.68E-12 0.0E+00 500 0 0.00 0. 0.
|
|
MCO3 + PO2
|
|
=1.000MO2 +1.000ALD2 +1.000CH2O +1.000HO2
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 598 1.87E-13 0.0E+00 500 0 0.00 0. 0.
|
|
MCO3 + A3O2
|
|
=1.000ACTA +1.000RCHO + +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 598 1.87E-13 0.0E+00 500 0 0.00 0. 0.
|
|
MCO3 + PO2
|
|
=1.000ACTA +0.350RCHO +0.650HAC +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 606 1.05E-14 0.0E+00 -2000 0 0.00 0. 0.
|
|
ISOP + O3
|
|
=0.387MACR +0.159MVK +0.100O3 +0.270OH
|
|
+0.070PRPE +0.900CH2O +0.060HO2 +0.150CO2
|
|
+0.050CO + + +
|
|
+ + + +
|
|
A 607 8.50E-16 0.0E+00 -1520 0 0.00 0. 0.
|
|
MVK + O3
|
|
=0.820MGLY +0.800CH2O +0.200O3 +0.050CO
|
|
+0.060HO2 +0.040ALD2 +0.080OH +
|
|
+ + + +
|
|
+ + + +
|
|
A 608 1.40E-15 0.0E+00 -2100 0 0.00 0. 0.
|
|
MACR + O3
|
|
=0.800MGLY +0.700CH2O +0.200O3 +0.200CO
|
|
+0.275HO2 +0.215OH +0.160CO2 +
|
|
+ + + +
|
|
+ + + +
|
|
A 621 3.15E-12 0.0E+00 -450 0 0.00 0. 0.
|
|
ISOP + NO3
|
|
=1.000INO2 + + +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
D 625 2.00E-14 0.0E+00 0 0 0.00 0. 0.
|
|
MVK + NO3
|
|
=1.000MVN2 + + +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 628 2.30E-15 0.0E+00 0 0 0.00 0. 0.
|
|
MACR + NO3
|
|
=1.000MAN2 + + +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 628 1.10E-15 0.0E+00 0 0 0.00 0. 0.
|
|
MACR + NO3
|
|
=1.000MAO3 +1.000HNO3 + +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 632 1.68E-12 0.0E+00 500 0 0.00 0. 0.
|
|
RCO3 + MO2
|
|
=1.000CH2O +1.000HO2 +1.000ETO2 +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 632 1.68E-12 0.0E+00 500 0 0.00 0. 0.
|
|
GCO3 + MO2
|
|
=2.000CH2O +2.000HO2 + +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 632 1.68E-12 0.0E+00 500 0 0.00 0. 0.
|
|
MAO3 + MO2
|
|
=1.000CH2O +1.000HO2 +1.000CH2O +1.000MCO3
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 632 1.68E-12 0.0E+00 500 0 0.00 0. 0.
|
|
GLCO3 + MO2
|
|
=1.000CH2O +2.000HO2 +1.000CO +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 633 1.87E-13 0.0E+00 500 0 0.00 0. 0.
|
|
RCO3 + MO2
|
|
=1.000RCOOH +1.000CH2O + +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 633 1.87E-13 0.0E+00 500 0 0.00 0. 0.
|
|
GCO3 + MO2
|
|
=1.000RCOOH +1.000CH2O + +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 633 1.87E-13 0.0E+00 500 0 0.00 0. 0.
|
|
MAO3 + MO2
|
|
=1.000RCOOH +1.000CH2O + +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 633 1.87E-13 0.0E+00 500 0 0.00 0. 0.
|
|
GLCO3 + MO2
|
|
=1.000RCOOH +1.000CH2O + +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 640 3.80E-12 0.0E+00 200 0 0.00 0. 0.
|
|
INPN + OH
|
|
=1.000INO2 + + +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 640 3.80E-12 0.0E+00 200 0 0.00 0. 0.
|
|
PRPN + OH
|
|
=1.000PRN1 + + +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 640 3.80E-12 0.0E+00 200 0 0.00 0. 0.
|
|
ETP + OH
|
|
=0.500OH +0.500ETO2 +0.500ALD2 +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 640 3.80E-12 0.0E+00 200 0 0.00 0. 0.
|
|
RA3P + OH
|
|
=0.500OH +0.500A3O2 +0.500RCHO +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 640 3.80E-12 0.0E+00 200 0 0.00 0. 0.
|
|
RB3P + OH
|
|
=0.500OH +0.500B3O2 +0.500ACET +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 640 3.80E-12 0.0E+00 200 0 0.00 0. 0.
|
|
R4P + OH
|
|
=0.500OH +0.500R4O2 +0.500RCHO +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 640 3.80E-12 0.0E+00 200 0 0.00 0. 0.
|
|
RP + OH
|
|
=0.500OH +0.500RCO3 +0.500ALD2 +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 640 3.80E-12 0.0E+00 200 0 0.00 0. 0.
|
|
PP + OH
|
|
=1.000PO2 + + +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 640 3.80E-12 0.0E+00 200 0 0.00 0. 0.
|
|
GP + OH
|
|
=1.000GCO3 + + +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 640 3.80E-12 0.0E+00 200 0 0.00 0. 0.
|
|
GLP + OH
|
|
=0.500OH +0.500GLCO3 +0.500CO +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 640 3.80E-12 0.0E+00 200 0 0.00 0. 0.
|
|
RIP + OH
|
|
=0.509IALD +0.509OH +0.491RIO2 +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 640 3.80E-12 0.0E+00 200 0 0.00 0. 0.
|
|
IAP + OH
|
|
=1.000IAO2 + + +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 640 3.80E-12 0.0E+00 200 0 0.00 0. 0.
|
|
ISNP + OH
|
|
=0.500OH +0.500RCHO +0.500NO2 +0.500ISN1
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 640 3.80E-12 0.0E+00 200 0 0.00 0. 0.
|
|
VRP + OH
|
|
=0.500OH +0.500RCHO +0.500VRO2 +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 640 3.80E-12 0.0E+00 200 0 0.00 0. 0.
|
|
MRP + OH
|
|
=1.000MRO2 + + +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 640 3.80E-12 0.0E+00 200 0 0.00 0. 0.
|
|
MAOP + OH
|
|
=1.000MAO3 + + +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 643 3.80E-12 0.0E+00 200 0 0.00 0. 0.
|
|
OH + MAP
|
|
=0.500OH +0.500CH2O +0.500MCO3 +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 644 1.40E-18 0.0E+00 0 0 0.00 0. 0.
|
|
C2H6 + NO3
|
|
=1.000ETO2 +1.000HNO3 + +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 646 8.00E-13 0.0E+00 -1000 0 0.00 0. 0.
|
|
MNO3 + OH
|
|
=1.000CH2O +1.000NO2 + +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 651 3.70E-11 0.0E+00 0 0 0.00 0. 0.
|
|
IALD + OH
|
|
=0.440IAO2 +0.410MAO3 +0.150HO2 +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 652 6.16E-15 0.0E+00 -1814 0 0.00 0. 0.
|
|
IALD + O3
|
|
=0.600MGLY +0.100OH +0.120CH2O +0.280GLYC
|
|
+0.300O3 +0.400CO +0.200H2 +0.200HAC
|
|
+0.200HCOOH + + +
|
|
+ + + +
|
|
A 715 2.50E-12 0.0E+00 500 0 0.00 0. 0.
|
|
MCO3 + MCO3
|
|
=2.000MO2 + + +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 716 1.80E-12 0.0E+00 500 0 0.00 0. 0.
|
|
MCO3 + MO2
|
|
=1.000CH2O +1.000MO2 +1.000HO2 +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 717 2.00E-13 0.0E+00 500 0 0.00 0. 0.
|
|
MCO3 + MO2
|
|
=1.000ACTA +1.000CH2O + +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 718 1.68E-12 0.0E+00 500 0 0.00 0. 0.
|
|
R4O2 + MCO3
|
|
=1.000MO2 +0.320ACET +0.190MEK +0.180MO2
|
|
+0.270HO2 +0.320ALD2 +0.130RCHO +0.050A3O2
|
|
+0.180B3O2 +0.320ETO2 + +
|
|
+ + + +
|
|
A 718 1.68E-12 0.0E+00 500 0 0.00 0. 0.
|
|
ATO2 + MCO3
|
|
=1.000MO2 +0.800HO2 +0.200CH2O +0.200MCO3
|
|
+0.800MGLY + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 718 1.68E-12 0.0E+00 500 0 0.00 0. 0.
|
|
KO2 + MCO3
|
|
=1.000MO2 +1.000ALD2 +1.000MCO3 +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 718 1.68E-12 0.0E+00 500 0 0.00 0. 0.
|
|
RIO2 + MCO3
|
|
=1.000MO2 +0.864HO2 +0.690CH2O +0.402MVK
|
|
+0.288MACR +0.136RIO1 +0.127IALD +
|
|
+ + + +
|
|
+ + + +
|
|
A 718 1.68E-12 0.0E+00 500 0 0.00 0. 0.
|
|
RIO1 + MCO3
|
|
=1.000MO2 +1.000IALD +1.000HO2 +0.750CH2O
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 718 1.68E-12 0.0E+00 500 0 0.00 0. 0.
|
|
IAO2 + MCO3
|
|
=1.000MO2 +1.000HO2 +0.650CO +0.180H2
|
|
+0.360HAC +0.260GLYC +0.580MGLY +0.400CH2O
|
|
+ + + +
|
|
+ + + +
|
|
A 718 1.68E-12 0.0E+00 500 0 0.00 0. 0.
|
|
ISN1 + MCO3
|
|
=1.000MO2 +1.000NO2 +1.000GLYC +1.000HAC
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 718 1.68E-12 0.0E+00 500 0 0.00 0. 0.
|
|
VRO2 + MCO3
|
|
=1.000MO2 +0.280HO2 +0.280CH2O +0.720MCO3
|
|
+0.720GLYC +0.280MGLY + +
|
|
+ + + +
|
|
+ + + +
|
|
A 718 1.68E-12 0.0E+00 500 0 0.00 0. 0.
|
|
MRO2 + MCO3
|
|
=1.000MO2 +1.000HO2 +0.170MGLY +0.830HAC
|
|
+0.830CO +0.170CH2O + +
|
|
+ + + +
|
|
+ + + +
|
|
A 718 1.68E-12 0.0E+00 500 0 0.00 0. 0.
|
|
B3O2 + MCO3
|
|
=1.000MO2 +1.000HO2 +1.000ACET +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 718 1.68E-12 0.0E+00 500 0 0.00 0. 0.
|
|
R4N1 + MCO3
|
|
=1.000MO2 +1.000NO2 +0.390CH2O +0.750ALD2
|
|
+0.570RCHO +0.300R4O2 + +
|
|
+ + + +
|
|
+ + + +
|
|
A 718 1.68E-12 0.0E+00 500 0 0.00 0. 0.
|
|
MVN2 + MCO3
|
|
=1.000MO2 +1.000NO2 +1.000CH2O +0.500MCO3
|
|
+0.500MGLY +0.500HO2 + +
|
|
+ + + +
|
|
+ + + +
|
|
A 718 1.68E-12 0.0E+00 500 0 0.00 0. 0.
|
|
MAN2 + MCO3
|
|
=1.000MO2 +1.000NO2 +1.000CH2O +1.000MGLY
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 718 1.68E-12 0.0E+00 500 0 0.00 0. 0.
|
|
INO2 + MCO3
|
|
=1.000MO2 +0.100NO2 +0.800HO2 +0.850HNO3
|
|
+0.050NO2 +0.100MACR +0.150CH2O +0.050MVK
|
|
+ + + +
|
|
+ + + +
|
|
A 718 1.68E-12 0.0E+00 500 0 0.00 0. 0.
|
|
PRN1 + MCO3
|
|
=1.000MO2 +1.000NO2 +1.000CH2O +1.000ALD2
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 719 1.87E-13 0.0E+00 500 0 0.00 0. 0.
|
|
R4O2 + MCO3
|
|
=1.000MEK +1.000ACTA + +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 719 1.87E-13 0.0E+00 500 0 0.00 0. 0.
|
|
ATO2 + MCO3
|
|
=1.000MEK +1.000ACTA + +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 719 1.87E-13 0.0E+00 500 0 0.00 0. 0.
|
|
KO2 + MCO3
|
|
=1.000MEK +1.000ACTA + +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 719 1.87E-13 0.0E+00 500 0 0.00 0. 0.
|
|
RIO2 + MCO3
|
|
=1.000MEK +1.000ACTA + +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 719 1.87E-13 0.0E+00 500 0 0.00 0. 0.
|
|
RIO1 + MCO3
|
|
=1.000MEK +1.000ACTA + +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 719 1.87E-13 0.0E+00 500 0 0.00 0. 0.
|
|
IAO2 + MCO3
|
|
=1.000MEK +1.000ACTA + +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 719 1.87E-13 0.0E+00 500 0 0.00 0. 0.
|
|
VRO2 + MCO3
|
|
=1.000MEK +1.000ACTA + +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 719 1.87E-13 0.0E+00 500 0 0.00 0. 0.
|
|
MRO2 + MCO3
|
|
=1.000MEK +1.000ACTA + +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 719 1.87E-13 0.0E+00 500 0 0.00 0. 0.
|
|
R4N1 + MCO3
|
|
=1.000RCHO +1.000ACTA +1.000NO2 +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 719 1.87E-13 0.0E+00 500 0 0.00 0. 0.
|
|
ISN1 + MCO3
|
|
=1.000RCHO +1.000ACTA +1.000NO2 +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 719 1.87E-13 0.0E+00 500 0 0.00 0. 0.
|
|
MVN2 + MCO3
|
|
=1.000RCHO +1.000ACTA +1.000NO2 +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 719 1.87E-13 0.0E+00 500 0 0.00 0. 0.
|
|
MAN2 + MCO3
|
|
=1.000RCHO +1.000ACTA +1.000NO2 +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 719 1.87E-13 0.0E+00 500 0 0.00 0. 0.
|
|
INO2 + MCO3
|
|
=1.000RCHO +1.000ACTA +1.000NO2 +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 719 1.87E-13 0.0E+00 500 0 0.00 0. 0.
|
|
PRN1 + MCO3
|
|
=1.000RCHO +1.000ACTA +1.000NO2 +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 719 1.87E-13 0.0E+00 500 0 0.00 0. 0.
|
|
B3O2 + MCO3
|
|
=1.000ACET +1.000ACTA + +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 720 1.68E-12 0.0E+00 500 0 0.00 0. 0.
|
|
MCO3 + ETO2
|
|
=1.000MO2 +1.000ALD2 +1.000HO2 +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 721 1.87E-13 0.0E+00 500 0 0.00 0. 0.
|
|
MCO3 + ETO2
|
|
=1.000ACTA +1.000ALD2 + +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 722 2.50E-12 0.0E+00 500 0 0.00 0. 0.
|
|
RCO3 + MCO3
|
|
=1.000MO2 +1.000ETO2 + +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 722 2.50E-12 0.0E+00 500 0 0.00 0. 0.
|
|
GCO3 + MCO3
|
|
=1.000MO2 +1.000HO2 +1.000CH2O +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 722 2.50E-12 0.0E+00 500 0 0.00 0. 0.
|
|
MAO3 + MCO3
|
|
=1.000MO2 +1.000CH2O +1.000MCO3 +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 722 2.50E-12 0.0E+00 500 0 0.00 0. 0.
|
|
GLCO3 + MCO3
|
|
=1.000MO2 +1.000HO2 +1.000CO +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 0 8.50E-13 0.0E+00 -2450 0 0.00 0. 0.
|
|
NO3 + NO3
|
|
=2.000NO2 +1.000O2 + +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 589 0.00E+00 0.0E+00 0 0 0.00 0. 0.
|
|
EMISSION +
|
|
=1.000NO + + +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 0 0.00E+00 0.0E+00 0 0 0.00 0. 0.
|
|
EMISSION +
|
|
=1.000NO2 + + +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 573 0.00E+00 0.0E+00 0 0 0.00 0. 0.
|
|
EMISSION +
|
|
=1.000CO + + +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 613 0.00E+00 0.0E+00 0 0 0.00 0. 0.
|
|
EMISSION +
|
|
=1.000ALK4 + + +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 588 0.00E+00 0.0E+00 0 0 0.00 0. 0.
|
|
EMISSION +
|
|
=1.000ISOP + + +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 0 0.00E+00 0.0E+00 0 0 0.00 0. 0.
|
|
EMISSION +
|
|
=1.000ACET + + +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 0 0.00E+00 0.0E+00 0 0 0.00 0. 0.
|
|
EMISSION +
|
|
=1.000PRPE + + +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 0 0.00E+00 0.0E+00 0 0 0.00 0. 0.
|
|
EMISSION +
|
|
=1.000C3H8 + + +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 0 0.00E+00 0.0E+00 0 0 0.00 0. 0.
|
|
EMISSION +
|
|
=1.000C2H6 + + +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 0 0.00E+00 0.0E+00 0 0 0.00 0. 0.
|
|
EMISSION +
|
|
=1.000MEK + + +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 0 0.00E+00 0.0E+00 0 0 0.00 0. 0.
|
|
EMISSION +
|
|
=1.000ALD2 + + +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 0 0.00E+00 0.0E+00 0 0 0.00 0. 0.
|
|
EMISSION +
|
|
=1.000CH2O + + +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 0 0.00E+00 0.0E+00 0 0 0.00 0. 0.
|
|
EMISSION +
|
|
=1.000O3 + + +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 0 0.00E+00 0.0E+00 0 0 0.00 0. 0.
|
|
EMISSION +
|
|
=1.000HNO3 + + +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 732 0.00E+00 0.0E+00 0 0 0.00 0. 0.
|
|
NO2 +
|
|
=1.000DRYDEP +1.000DRYNO2 + +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 744 0.00E+00 0.0E+00 0 0 0.00 0. 0.
|
|
O3 +
|
|
=1.000DRYDEP +1.000DRYO3 + +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 726 0.00E+00 0.0E+00 0 0 0.00 0. 0.
|
|
PAN +
|
|
=1.000DRYDEP +1.000DRYPAN + +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 733 0.00E+00 0.0E+00 0 0 0.00 0. 0.
|
|
HNO3 +
|
|
=1.000DRYDEP +1.000DRYHNO3 + +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 0 0.00E+00 0.0E+00 0 0 0.00 0. 0.
|
|
CH2O +
|
|
=1.000DRYDEP +1.000DRYCH2O + +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 0 0.00E+00 0.0E+00 0 0 0.00 0. 0.
|
|
N2O5 +
|
|
=1.000DRYDEP +1.000DRYN2O5 + +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 0 0.00E+00 0.0E+00 0 0 0.00 0. 0.
|
|
H2O2 +
|
|
=1.000DRYDEP +1.000DRYH2O2 + +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 0 0.00E+00 0.0E+00 0 0 0.00 0. 0.
|
|
PMN +
|
|
=1.000DRYDEP +1.000DRYPMN + +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 0 0.00E+00 0.0E+00 0 0 0.00 0. 0.
|
|
PPN +
|
|
=1.000DRYDEP +1.000DRYPPN + +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 0 0.00E+00 0.0E+00 0 0 0.00 0. 0.
|
|
R4N2 +
|
|
=1.000DRYDEP +1.000DRYR4N2 + +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 0 3.30E+01 2.0E-01 0 0 K 0.00 0. 0.
|
|
HO2 +
|
|
=0.500H2O2 + + +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 0 4.60E+01 1.0E-04 0 0 K 0.00 0. 0.
|
|
NO2 +
|
|
=0.500HNO3 +0.500HNO2 + +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 415 6.20E+01 1.0E-03 0 0 K 0.00 0. 0.
|
|
NO3 +
|
|
=1.000HNO3 + + +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 415 1.08E+02 1.0E-01 0 0 K 0.00 0. 0.
|
|
N2O5 +
|
|
=2.000HNO3 + + +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 801 1.10E-11 0.0E+00 -240 0 0.00 0. 0.
|
|
DMS + OH
|
|
=1.000SO2 +1.000MO2 +1.000CH2O +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 802 1.00E-39 0.0E+00 5820 1 G 0.00 0. 0.
|
|
5.00E-30 0.0E+00 6280 0 0.00 0. 0.
|
|
DMS + OH O2
|
|
=0.750SO2 +0.250MSA +1.000MO2 +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 803 1.90E-13 0.0E+00 500 0 0.00 0. 0.
|
|
DMS + NO3
|
|
=1.000SO2 +1.000HNO3 +1.000MO2 +1.000CH2O
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 804 3.30E-31 4.3E+00 0 1 P 0.60 0. 0.
|
|
1.60E-12 0.0E+00 0 0 0.00 0. 0.
|
|
SO2 + OH M
|
|
=1.000SO4 +1.000HO2 + +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
9999 0.00E-00 0.0 0 0 0.00 0. 0.
|
|
END KINETIC
|
|
+ + +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
|
|
#=============================================================================
|
|
# Photolysis reactions
|
|
#=============================================================================
|
|
|
|
BEGIN
|
|
A 2 3.61E+01 0.0 0 0 Q 0.00 0. 0.
|
|
O3 +
|
|
=1.000OH +1.000OH + +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 20 3.51E+01 0.0 0 0 0.00 0. 0.
|
|
NO2 +
|
|
=1.000NO +1.000O3 + +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 31 3.81E+01 0.0 0 0 0.00 0. 0.
|
|
H2O2 +
|
|
=1.000OH +1.000OH + +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 54 3.01E+01 0.0 0 0 0.00 0. 0.
|
|
MP +
|
|
=1.000CH2O +1.000HO2 +1.000OH +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 59 4.01E+01 0.0 0 0 0.00 0. 0.
|
|
CH2O +
|
|
=1.000HO2 +1.000HO2 +1.000CO +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 60 4.02E+01 0.0 0 0 0.00 0. 0.
|
|
CH2O +
|
|
=1.000H2 +1.000CO + +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 63 4.31E+01 0.0 0 0 0.00 0. 0.
|
|
HNO3 +
|
|
=1.000OH +1.000NO2 + +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 69 3.01E+01 0.0 0 0 0.00 0. 0.
|
|
HNO2 +
|
|
=1.000OH +1.000NO + +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 74 3.01E+01 0.0 0 0 0.00 0. 0.
|
|
HNO4 +
|
|
=1.000OH +1.000NO3 + +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 77 3.72E+01 0.0 0 0 0.00 0. 0.
|
|
NO3 +
|
|
=1.000NO2 +1.000O3 + +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 78 3.71E+01 0.0 0 0 0.00 0. 0.
|
|
NO3 +
|
|
=1.000NO +1.000O2 + +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 84 3.42E+01 0.0 0 0 0.00 0. 0.
|
|
N2O5 +
|
|
=1.000NO3 +1.000NO2 + +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 84 3.41E+01 0.0 0 0 0.00 0. 0.
|
|
N2O5 +
|
|
=1.000NO3 +1.000NO +1.000O3 +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 426 3.02E+01 0.0 0 0 T 0.00 0. 0.
|
|
HNO4 +
|
|
=1.000HO2 +1.000NO2 + +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 440 3.02E+01 0.0 0 0 0.00 0. 0.
|
|
ALD2 +
|
|
=1.000MO2 +1.000HO2 +1.000CO +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 441 3.01E+01 0.0 0 0 0.00 0. 0.
|
|
ALD2 +
|
|
=1.000CH4 +1.000CO + +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 457 4.11E+01 0.0 0 0 0.00 0. 0.
|
|
PAN +
|
|
=0.600MCO3 +0.600NO2 +0.400MO2 +0.400NO3
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 467 3.01E+01 0.0 0 0 0.00 0. 0.
|
|
RCHO +
|
|
=1.000ETO2 +1.000HO2 +1.000CO +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 469 3.01E+01 0.0 0 0 0.00 0. 0.
|
|
ACET +
|
|
=1.000MCO3 +1.000MO2 + +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 469 3.02E+01 0.0 0 0 0.00 0. 0.
|
|
ACET +
|
|
=2.000MO2 +1.000CO + +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 475 3.01E+01 0.0 0 0 0.00 0. 0.
|
|
MEK +
|
|
=0.850MCO3 +0.850ETO2 +0.150MO2 +0.150RCO3
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 484 3.01E+01 0.0 0 0 0.00 0. 0.
|
|
MNO3 +
|
|
=1.000CH2O +1.000H2O +1.000NO2 +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 510 3.01E+01 0.0 0 0 0.00 0. 0.
|
|
GLYC +
|
|
=1.000CH2O +2.000HO2 +1.000CO +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 527 3.01E+01 0.0 0 0 0.00 0. 0.
|
|
GLYX +
|
|
=0.500H2 +1.000CO +0.500CH2O +0.500CO
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 529 3.02E+01 0.0 0 0 0.00 0. 0.
|
|
GLYX +
|
|
=2.000CO +2.000HO2 + +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 535 3.01E+01 0.0 0 0 0.00 0. 0.
|
|
MGLY +
|
|
=1.000MCO3 +1.000CO +1.000HO2 +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 535 3.02E+01 0.0 0 0 0.00 0. 0.
|
|
MGLY +
|
|
=1.000ALD2 +1.000CO + +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 603 3.01E+01 0.0 0 0 0.00 0. 0.
|
|
MVK +
|
|
=1.000PRPE +1.000CO + +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 603 3.02E+01 0.0 0 0 0.00 0. 0.
|
|
MVK +
|
|
=1.000MCO3 +1.000CH2O +1.000CO +1.000HO2
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 603 3.03E+01 0.0 0 0 0.00 0. 0.
|
|
MVK +
|
|
=1.000MO2 +1.000MAO3 + +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 604 3.01E+01 0.0 0 0 0.00 0. 0.
|
|
MACR +
|
|
=1.000MAO3 +1.000HO2 + +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 604 3.02E+01 0.0 0 0 0.00 0. 0.
|
|
MACR +
|
|
=1.000CO +1.000HO2 +1.000CH2O +1.000MCO3
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 605 2.61E+01 0.0 0 0 0.00 0. 0.
|
|
HAC +
|
|
=1.000MCO3 +1.000CH2O +1.000HO2 +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 642 2.41E+01 0.0 0 0 0.00 0. 0.
|
|
INPN +
|
|
=1.000OH +1.000HO2 +1.000RCHO +1.000NO2
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 642 2.41E+01 0.0 0 0 0.00 0. 0.
|
|
PRPN +
|
|
=1.000OH +1.000HO2 +1.000RCHO +1.000NO2
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 642 2.41E+01 0.0 0 0 0.00 0. 0.
|
|
ETP +
|
|
=1.000OH +1.000HO2 +1.000ALD2 +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 642 2.41E+01 0.0 0 0 0.00 0. 0.
|
|
RA3P +
|
|
=1.000OH +1.000HO2 +1.000RCHO +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 642 2.41E+01 0.0 0 0 0.00 0. 0.
|
|
RB3P +
|
|
=1.000OH +1.000HO2 +1.000ACET +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 642 2.41E+01 0.0 0 0 0.00 0. 0.
|
|
R4P +
|
|
=1.000OH +1.000HO2 +1.000RCHO +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 642 2.41E+01 0.0 0 0 0.00 0. 0.
|
|
PP +
|
|
=1.000OH +1.000HO2 +1.000ALD2 +1.000CH2O
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 642 2.41E+01 0.0 0 0 0.00 0. 0.
|
|
RP +
|
|
=1.000OH +1.000HO2 +1.000ALD2 +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 642 2.41E+01 0.0 0 0 0.00 0. 0.
|
|
GP +
|
|
=1.000OH +1.000HO2 +1.000CH2O +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 642 2.41E+01 0.0 0 0 0.00 0. 0.
|
|
GLP +
|
|
=1.000OH +1.000HO2 +1.000CO +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 642 2.41E+01 0.0 0 0 0.00 0. 0.
|
|
RIP +
|
|
=1.000OH +1.000HO2 +0.627CH2O +0.368MVK
|
|
+0.259MACR +0.373IALD + +
|
|
+ + + +
|
|
+ + + +
|
|
A 642 2.41E+01 0.0 0 0 0.00 0. 0.
|
|
IAP +
|
|
=1.000OH +1.000HO2 +0.670CO +0.190H2
|
|
+0.360HAC +0.260GLYC +0.580MGLY +
|
|
+ + + +
|
|
+ + + +
|
|
A 642 2.41E+01 0.0 0 0 0.00 0. 0.
|
|
ISNP +
|
|
=1.000OH +1.000HO2 +1.000RCHO +1.000NO2
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 642 2.41E+01 0.0 0 0 0.00 0. 0.
|
|
VRP +
|
|
=1.000OH +0.300HO2 +0.300CH2O +0.700MCO3
|
|
+0.700GLYC +0.300MGLY + +
|
|
+ + + +
|
|
+ + + +
|
|
A 642 2.41E+01 0.0 0 0 0.00 0. 0.
|
|
MRP +
|
|
=1.000OH +1.000HO2 +1.000HAC +0.500CO
|
|
+0.500CH2O + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 642 2.41E+01 0.0 0 0 0.00 0. 0.
|
|
MAOP +
|
|
=1.000OH +1.000CH2O +1.000MCO3 +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
A 649 2.51E+01 0.0 0 0 0.00 0. 0.
|
|
R4N2 +
|
|
=1.000NO2 +0.320ACET +0.190MEK +0.180MO2
|
|
+0.270HO2 +0.320ALD2 +0.130RCHO +0.050A3O2
|
|
+0.180B3O2 +0.320ETO2 + +
|
|
+ + + +
|
|
A 667 2.41E+01 0.0 0 0 0.00 0. 0.
|
|
MAP +
|
|
=1.000OH +1.000MO2 + +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|
|
9999 0.00E-00 0.0 0 0 0.00 0. 0.
|
|
END PHOTOLYSIS
|
|
+ + +
|
|
+ + + +
|
|
+ + + +
|
|
+ + + +
|